May 21, 2020
Uranium, classified as a chemical element, is identified by the symbol U and has an atomic mass of 238. In nature, it is found in the form of three isotopes: U234, U235 and U238. It is the natural element with the highest atomic number. It is surpassed only by artificial radioactive elements (transuranics) such as neptunium and plutonium. It is a radioactive element and belongs to the actinide group.
Uranium is a fairly common element on Earth, incorporated into the planet during its formation, and is considered to be more abundant than mercury, antimony, silver and cadmium and as abundant as molybdenum and arsenic.
It is believed to be the product of the decay of elements with even higher atomic numbers that existed at some time in the Universe. It can be recognised as a silvery radioactive metal, malleable, ductile and less hard than steel, which, when exposed to air, forms an oxide layer on its surface.
Uranium can be found in various types of deposits. The most common and important form of ore is uraninite, made up of a mixture of UO2 and U3O8. Other uranium-bearing minerals include autunite, carnotite, branerite, torbernite and others.
Its main commercial application is the generation of electricity, as fuel for nuclear power reactors. To do this, it goes through a series of stages and processes, including mining beneficiation and the production of the fuel element, made up of uranium dioxide pellets.
Uranium ore is known worldwide and exploited in rocks of Archaean to recent ages and in the most diverse geological environments, from deposits related to albitites in Proterozoic rocks, to sands in recent sedimentary basins, placer-type surface deposits and concentration by weathering processes.
The recently updated IAEA (International Atomic Energy Agency) UDEPO (World Distribution of Uranium Deposits) database includes information on 1807 known uranium deposits in the world, 20 of which are in Brazil. The deposits are classified into 15 typologies and 37 subtypes.
Despite Brazil's vast territory and the diversity of geological environments, deposits are known in only 7 of the typologies classified by the IAEA, half of which are related to intrusive rocks or metasomatism.
Uranium occurs in various minerals such as uraninite (a complex uranate of uranyl and lead, which can contain lanthanum, thorium and yttrium. Also called pitchblende), carnotite (potassium and sodium uranovanadate), autunite (hydrated uranium-calcium phosphate), torbernite (hydrated uranium-copper phosphate), zeunerite (hydrated copper-uranium arsenate).
It can also be found in rocks with phosphates, in lignite (fossil coal, an intermediate stage between peat and bituminous coal) and in sands with monazite (phosphate of cerium, lanthanum, praseodymium, neodymium, with thorium oxide).
Uranium is a silver-coloured metal and its main form of occurrence is uraninite (UO2). Primary or secondary varieties of uranium minerals come in a variety of colours such as yellow (uranophane, carnotite, autunite) and green (tobernite).
The German pharmacist Martin Klaproth became the first scientist to discover uranium, naming the chemical element in honour of the planet Uranus (the penultimate in the Solar System counting from the Sun). Despite this, its use, at least in oxide form, has been known for a long time, since a yellow glass, dated 79 AD, was found in Naples, Italy containing around 1% uranium oxide.
The element was later isolated from the mineral by the Frenchman Eugene-Melchior Peligot in 1841 by reducing anhydrous chloride with potassium.
The Frenchman A. Henri Becquerel discovered in 1896 that uranium had radioactive properties during an attempt to show the relationship between X-rays and the luminescence of uranium salts by placing a quantity of uranium salt on a photographic plate wrapped in black paper and exposed to sunlight. After developing the plate, it became clear that the rays emitted by the salt passed through the black paper.
Later, when he repeated the experiment, Becquerel, unable to find good sunlight conditions, put the material away in a drawer. When Becquerel picked up the material again to restart his research, he observed an intense image on the plate. He repeated the experiment in total darkness, obtaining the same result, proving that the uranium salts emitted rays that affected the photographic plate without it being exposed to sunlight.
Becquerel thus discovered the radioactivity of uranium. The discovery of nuclear fission by the Germans Otto Hahn and Fritz Strassman in 1939 made uranium an element of great importance.
Uranium ore serves various industrial sectors by supplying raw materials to the steel, automotive, optical fibre and special ceramics industries. Until World War II, uranium ores were only a commercial source of radium (Ra).
Uranium salts had limited applications (photography, ceramics). With the development of the nuclear industry, uranium began to be used in weapons and nuclear reactors. Today, although it is also used in medicine and agriculture, its main commercial application is in electricity generation, as fuel for nuclear power reactors.
Thus, the global demand for uranium is made up of several countries that use nuclear energy in their energy matrix.
Law 4.118 of 1962 was created to regulate the National Nuclear Energy Policy and create the National Nuclear Energy Commission (CNEN). This law became famous as the "Monopoly Law" and the reason for this can be seen in its first article:
Art. 1 Constitutes a monopoly of the Union:
I - The research and exploitation of nuclear mineral deposits located in the national territory;
II - Trade in nuclear ores and their concentrates; nuclear elements and their compounds; fissile and fertile materials, artificial and substantial radioisotopes and radioactive substances of the three natural series; nuclear by-products;
III - The production of nuclear materials and their industrialisation.
As this law predates the current Constitution, it also has an exclusive article on the subject:
Art. 177. The following constitute a monopoly of the Union:
V - the research, mining, enrichment, reprocessing, industrialisation and trade of nuclear ores and minerals and their derivatives, with the exception of radioisotopes whose production, commercialisation and use may be authorised under a permission regime, in accordance with subparagraphs b and c of item XXIII of the caput of Art. 21 of this Federal Constitution.
In this way, uranium mineral research and all its stages, in the Brazilian context, are the exclusive preserve of the Federal Government, in the form of its state-owned nuclear industries.
The monopoly situation in Brazil was not exclusive to uranium and in past decades other sectors faced the same discussion, the most notable being the telecoms and oil sectors, with oil in a similar situation to uranium.
The premises of the monopoly are laid down in the Federal Constitution:
Art. 21. It is incumbent upon the Union:
XXIII - to explore nuclear services and installations of any nature and to exercise a state monopoly over research, mining, ..., subject to the following principles and conditions:
a) all nuclear activity in national territory shall only be permitted for peaceful purposes and with the approval of the National Congress;
b) under a concession or permission regime, the use of radioisotopes is authorised for research and medicinal, agricultural, industrial uses and similar activities;
c) civil liability for nuclear damage is independent of fault;
Points b and c are interesting points to scrutinise the legislation and its practical effects.
In a brief and exemplary way, the legal effect of point c is to make the Union responsible for practically any nuclear accident, whether or not the perpetrator is at fault, and this has already had serious repercussions in Brazil's past, such as the well-known Cesium-137 accident in Goiás and the suspicions of radioactive contamination around state-owned nuclear companies.
Point b is of greater interest to our sector. After a long battle, the industrial sector, including the agricultural, pharmaceutical and mining industries, managed to break the monopoly on the use of radioisotopes in October 2006, with Constitutional Amendment 49 of 2006.
In the food sector , radiation equipment is used to increase the durability of food by altering certain organic chains, making them less susceptible to degradation.
In our sector, mining companies use spectrometers with different functionalities such as X-ray fluorescence, atomic absorption and X-ray diffractometers, which use thorium, radium or other radioactive element tubes and are vital for the chemical, mineralogical and structural analysis of mineral resources.
Technological developments in the sector already allow chemical analyses to be carried out by sensors on conveyor belts, calibrating mineral processing models or even carrying out pre-concentration, as in the case of ore-sorting.
In Brazil, the most important source of nuclear resources is the Lagoa Real Uraniferous District, which is located in a region marked by past orogenic events in the centre-south of Bahia, about 20 km from the city of Caetité.
In addition to this mine, in the past, between 1981 and 1995, the Poços de Caldas mine produced around 1,200 tonnes of uranium concentrate. This mine had an average content of 800 PPM (parts per million), a much lower quality than that observed in Caetité (with the potential to reach 3,000 PPM).
After a campaign, between 1976 and 1977, of generic aerogeophysical surveys by the Brazilian Geological Service, CPRM - Companhia de Pesquisa de Mineral Resources - 19 targets with potential for uranium were identified as mineral occurrences.
The studies gained momentum with the creation of NUCLEBRÁS in December 1974, the advent of the "first oil crisis" in 1973, driving the search for new sources of energy and aerospectrometry work confirming 33 uranium occurrences. The allocation of specific financial resources for the search for uranium increased, coming from the Brazilian Nuclear Programme.
The focus encompassed prospecting, research, the development of working methods and techniques and the mining of uranium deposits in the country, resulting in the revelation of the Itatiaia deposits in Santa Quitéria in Ceará - a deposit with the potential to produce high-grade limestone and phosphate together with uranium- and Lagoa Real in Caetité in Bahia. Only Lagoa Real became a mine and is still active.